So here's my thinking on the subject....Yes. Older cues sometimes used brass pins or mild steel pins because they were readily available as "all-thread." As such that all-thread would have been 5/16-18 because 5/16-14 is not a typical thread pitch in any machine application. The only industry I've ever seen use 5/16-14 is the pool cue world. It's a complete abomination. That being said any cue maker who took it upon himself to actually make 5/16-14 pins (I'm assuming here) would most likely have done so using stainless because the cost difference between stainless and mild steel is so damn nominal it would make no sense to use an inferior material....mild steel. For instance: go to MSC's catalog and type in 5/16-18 and look at the sheer number of bolts, nuts, taps, pins etc., that are available. Now...try that with 5/16-14. For the most part it doesn't exist in the machine tools world. How and why it ever came about is anyone's guess but it's surmised it was so you could screw the cue together just a tad faster (or get out of Dodge faster). Either that or that pitch of pin would make it so you had to return the cue to the maker in order to get additional shafts or have work done on the cue. So...since we know that 5/16-18 exists in the machine tools world it's absolutely available in stainless steel so buying mild steel and then plating it is....well.....it's just silly. The cost of plating a 5/16-18 pin would easily exceed the cost of just buying a that pin in stainless.
3/18-10 pins do exist in the machine tool world but let's resign ourselves to the 14/18 TPI argument for the time being. Here's a quick guide to understanding thread tolerances that you may find interesting:
https://sizes.com/tools/bolts_inch_threadFit.htm My argument is that pretty much the higher classes of pin minor/major diameters is rather irrelevant since the insert itself is much more adaptable to changes in thread tolerances. Hell....it's brass....soft, yellow brass. It's much MUCH easier to purchase a tap that will accommodate any thread pitch deviations than it is to try plating a pin in order to make it fit snugly into an insert. Back then, in my opinion, super hiigh tolerances of the pin vs. insert were for the most part rather unnecessary. The pin acts as a drawing device for the shaft and that's about it. In a high tolerance environment the tiniest spec of dirt, even one that's .0005 will cause the pin to seize OR it'll recut or deform the brass insert threads (dissimilar materials) even if that pin was made from mild steel.
So, let's assume you're now a cuemaker and you order a bunch of 5/16-14 pins custom made because they don't exist anywhere in the machine world as an off the shelf product and an equal number brass inserts. Typical chrome plating will deposit material that's roughly .001 to .025 of an inch in thickness. Would YOU the cuemaker....prefer to take a pin, fit it to a brass insert only to determine it's too sloppy, plate it an additional .004 fit it again, still too sloppy then plate it again with another .004 only to discover it's too tight THEN polish it back to .006 total ORRRRRRRRRRRRRRRRRRRRRRRRRRR would you run in an incremental tap into the soft brass insert a few times and call it a day???? Now.....with that perfectly mated pin and brass insert combination.....please make sure you hermetically seal them at the end of a session because if you get the slightest bit of dirt, grime, chalk, etc., on either piece they simply will NOT fit the next time you play.
Vince.
p.s. Brevity has never been my strong point. Sorry.