Visualize the line from center of object ball to desired point of impact(usually pocket) and a second line(tangent line) at 90 degrees to the first line. Visually bisect(divide by 2) the 90 degree angle formed by the 2 lines using your cue as a guide if necessary and you will have the 45 degree line. Look to see where your cue ball lies in position to the 45 degree angle line and you can make a quick guess at the angle of the shot. You can also bisect the 45 degree angle on either side and end up with a 0, 22.5, 45, 67.5 and 90 degree reference lines to estimate the angle. It shouldn't take long before you brain can quickly determine the angle of the shot within a couple degrees by just looking looking at it.