sand binders
bandido said:
Another term for it is binder. Do a websearch on sand casting and you may find the specific name of the chemical.
I use bentonite clay as a binder for my sand casting. It might work for making chalk, if you got a good mix and baked it well. IIRC I use about 2 or 3% bentonite to silica, plus a bit of moisture (water)to get it to bind. Of course this is NOT baked, rather left wet as green sand. The bond is fine for that purpose, but perhaps a different ratio would be better for a baked cube. Now that I think about it, baked cores can be made with this recipe, but increase the bentonite a bit, and instead of straight water, use "molasses water", which is water with about 5% molasses mixed in. Not only will the baked cube be a bit harder, but your chalk will smell nicer too !
Another alternative might be to soak the silica in waterglass (forget the chemical name, hey, I'm an electrical engineer, not a chem!), then blow carbon dioxide through it. This might get too hard though, whereas I think the bentonite might be too crumbly.
WRT silica, I use sand blasting silica, and the Sil-0 might be fine enough for chalk. Drop by a good building / industrial supply place and see, the stuff always leaks out of the bag ... The Sil-1 and up are definately too course compared to the dust I get off a piece of chalk.
Dave
BTW, if you want to try this, and need materials, let me know via PM, maybe I can send you some of my clay. If you can find bentonite localy, great. I have a 50 lb bag with 49 lbs left, and it cost me about 8$ Canadian. Of course around here some people know bentonite as 'dirt'

Waterglass is available at finer drug stores, and carbon dioxide at your local welders or fountain-drink-dispenser.